As a 'pure chemist' you might prefer the STR for such a
'normal' reaction. That is not bad, as long as the reaction is not too fast for
your sensing device and when you are willing to carry out some additional
evaluation work: you get the concentration/time curve and can calculate
directly the conversion, but for the reaction rate you have to do a graphical
or numerical differentiation of the C(t) curve. You know the rest of the
evaluation: plot ln r versus ln c and get the order as ascent and ln k as
Y-intersection. For fast reactions you are advised to take a TFR: 'Continuous Flow Method'. But as a
chemist with reaction engineering knowledge you should prefer a CSTR for the
'normal' case, mainly when very much measurements have to be carried out and
much data is to be acquired. Why ? From the reactor equation:
tR = tau = CA,0(U/-r)
follows: -r =
CA,0(U/tau)
and with the definition of the conversion we
get:
-r = (CA,0- Cstat) /tau
this means
that we are measuring the reaction rate more or less 'directly' with the
stationary concentration of educt A in the CSTR. The rest of the kinetic
evaluation is as usual (see my task
as an example). And here we have also some 'connection' to the
differential loop reactor: if you operate this reactor with high recirculation
rates, the reactor can be calculated with the CSTR-balance. This brings forth
the same ease of getting directly the reaction rate, - that is very practical
for heterogeneous (catalytic) reactions, as in this case you have to regard
much more 'additional effects' like for instance catalyst deactivation
behaviour and mass transfer (liquid film and pore diffusion)
etc.
By the way: it is also important to realize that the thermal conduction of the process (see e.g. an overview) is much more easy in the CSTR than in the other reactor types, you can operate the reactor much more precisly isothermal than the others.
The only disadvantage of the continuous reactors is that you need 'by far' more chemicals as in the case of the batch.
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