Why is the optimal space time for the production of the intermediate product B in a consecutive reaction shorter in not-back-mixed reactors in comparison to the back-mixed CSTRs ?

Let's try a very short qualitative explanation: The reaction kinetic demands an exact reaction time tauopt corresponding to Bmax. In a not-back-mixed reactor the reaction time is not shorter and not longer than the residence time, and therefore it is optimal when residence time = tauopt.

In a CSTR we have a residence time distribution, i.e. there are 'portions' of the reaction mass that 'reside' longer and portions that reside shorter than tauopt in the reaction vessel. Therefore we don't operate for the whole reaction mixture at exact the optimum reaction time.

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