The optimization strategies for space time (yield)
The strategy depends on the 'essence' of the chemical reaction
- Let us call a first type of reactions
'simple reactions', where the
rate and quantity of our product formed from the educt is linked
only
to the conversion ( i.e. directly and in a steady function). Here we have to chose
only a very high conversion and a contacting
pattern, which provides an optimal space time. (Remember: in this
case an optimal space time can be reached in reactors without back-mixing (i.e. not back-mixed in
both space and time):
batch reactor and tubular flow reactor. Can you explain this
statement? - No?
)
We can call this optimizing
strategy:
'conversion orientated strategy'
(german:
'Umsatzorientierte Strategie')
- The second type of reaction is the more
'complex' type, where the
product formation is not simply linked to the conversion of educt(s). All sorts
of complex reaction networks are belonging to this type. Very often selectivity
problems are encountered as a consequence of several (possible) reaction paths.
Comprehensive examples are simple parallel
(snapshot) and consecutive
(snapshot) as well as autocatalytic reactions. Examples and further details will be given in later questions and
in various simulations. In the case of these 'complex' reactions we are forced
to maintain required concentration levels in 'specific volume parts' at
'specific times'. We have to optimize space time yield by controlling
concentration levels. This process is of course more complicated, but in
general the optimization process can be carried out by using the possibilities
of the choice and adjustment of the contacting pattern, i.e. (as we call it)
the macro-mixing conditions. We can use a variety of reactor combinations to reach a
desired contacting pattern. The local degree of back-mixing is the important
item.
We can call this optimizing strategy:
'strategy of controlling concentration levels'
(german:
'Konzentrationsführungs - Strategie')
- Summary on the optimization
- Last not least it should be kept in the mind that the
influence of temperature and catalysts provides very powerful tools for the
enhancement of product yields.
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