A reversible reaction has reached the equilibrium when
rA = 0, i.e. dUA/dt = 0
When you write the
kinetic differential equation for the reaction and substitute the concentration
by the conversion UA, you get the maximum conversion for dU/dt = r =
0 :
UA,max =
k1/(k1+k2)
You can rearrange this
equation to give k2 and substitute k2 in the basic
kinetic equation :
dUA/dt = k1( 1- UA/UA,max)
You can solve this differential equation and get by integration in the boarders UA = 0 to 0.9* UA,max the time that the reaction takes to reach 90% of the equilibrium conversion.
On the other hand you can carry out the (simulation) and take the control values for comparison.
take your browser back for previous text or: