The equilibrium conversion of a reversible reaction

A reversible reaction has reached the equilibrium when rA = 0, i.e. dUA/dt = 0

When you write the kinetic differential equation for the reaction and substitute the concentration by the conversion UA, you get the maximum conversion for dU/dt = r = 0 :

UA,max = k1/(k1+k2)

You can rearrange this equation to give k2 and substitute k2 in the basic kinetic equation :

dUA/dt = k1( 1- UA/UA,max)

You can solve this differential equation and get by integration in the boarders UA = 0 to 0.9* UA,max the time that the reaction takes to reach 90% of the equilibrium conversion.

On the other hand you can carry out the (simulation) and take the control values for comparison.

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