The following terms in the general heat balance have to be omitted
for:
-
adiabatic reactors:
-
adiabatic STR,
'cancel' : term (IIa) and (IIb) =
convective term; term (IV) = heat exchange ;
realize: * the heat 'goes into' the reaction mass via the
instationary term (I)
-
adiabatic CSTR,
'cancel': term (I) = instationary
term; term (IV) = heat exchange;
realize: * there is
no strict adiabatic behaviour, as heat is transported by the convective flow:
'adiabatic' means here 'without heat exchange'. Heat 'goes' also into the
reaction mass, but temperature rests constant (isothermal behaviour) when
stationarity is reached.
-
adiabatic TFR,
'cancel': term (I) = instationary
term; term (IV) = heat exchange;
realize: the balance 'convective term =
reaction term' can be rewritten in a balance for a differential volume element.
The convective term 'overtakes' here the role of the instationary term in the
adiabatic STR.
-
not adiabatic reactors
-
continuous reactors,
'cancel': term (I) =
instationary term
-
batch STR,
'cancel': term (II) = convective
flow
see a blackbord sketch of the various
possibilities for the 3 basic reactor types
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